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Palladium(II) and Platinum(II) Halide Complexes with 2,2''-Thiodiacetophenone Derivatives
Sandhu, Sarjit Singh,Tandon, Santokh Singh,Singh, Harjit
, p. 851 - 853 (2007/10/02)
2,2''-Thiodiacetophenones (D) form 2:1 and 1:1 complexes with palladium(II) halides and platinum(II) chloride, having the general formulae MX2(D)2 and 2 respectively.On the basis of IR and far IR and electronic spectral data, these complexes have been assigned square planar stereochemistry, with coordination through sulphur atom.The carbonyl oxygen atoms are not involved in coordination.However, in 2 bridging through chloride ions gives a binuclear complex.
