80314-44-9

Upstream product

• 156-39-8 4-hydroxyphenylpiruvic acid 
• 58484-84-7 p-Hydroxyphenylpyruvic acid O-methyloxim 
• 13990-07-3 (3,5-dibromo-4-hydroxy-phenyl)-pyruvic acid 
• 593-56-6 N-methoxylamine hydrochloride 

Downstream Products

• 862479-46-7 3-[4-(9-bromo-3-methoxyimino-2,8-dioxo-1-oxaspiro[4.5]deca-6,9-dien-7-yloxy)-3,5-dibromophenyl]-2-(methoxyimino)propionic acid 
• 80314-45-0 3-(3,5-Dibromo-4-hydroxy-phenyl)-2-[(Z)-methoxyimino]-propionic acid methyl ester 
• 80314-47-2 3-[(S)-3-Bromo-5-(2,6-dibromo-4-{2-methoxycarbonyl-2-[(Z)-methoxyimino]-ethyl}-phenoxy)-1-methoxy-4-oxo-cyclohexa-2,5-dienyl]-2-[(Z)-methoxyimino]-propionic acid methyl ester 

Relevant academic research and scientific papers

Efficient total synthesis of bastadin 6, an anti-angiogenic brominated tyrosine-derived metabolite from marine sponge

An efficient total synthesis of bastadin 6 (1), a cyclic tetramer of brominated tyrosine derivatives from the marine sponge, Ianthella basta, with selective anti-angiogenic activity, was accomplished. We developed a novel Ce(IV)-mediated oxidative couplin

BIOMIMETIC OXIDATION OF METHYL 3,5-DIBROMO-4-HYDROXYPHENYLPYRUVATE OXIME AND RELATED PHENOLS

Methyl 3,5-dibromo-4-hydroxyphenylpyruvate oxime and related phenols were subjected to oxidation using thallium (III) nitrate as well as to anodic oxidation to afford the corresponding spiro-isoxazols, dimeric compounds, and others.