80317-56-2

Upstream product

• 24654-54-4 3-(4-chlorophenyl)-2-methyl-2-propenal 
• 104-88-1 4-chlorobenzaldehyde 

Downstream Products

• 80317-57-3 1-chloro-4-(3-chloro-2-methyl-1-propenyl)benzene 
• 80317-44-8 2-<<3-(4-chlorophenyl)-2-methyl-1-<(tetrahydro-2H-pyran-2-yl)methyl>-2-propenyl>thio>-1-methyl-1H-imidazole 
• 80317-41-5 2-<<3-(4-chlorophenyl)-1,2-dimethyl-2-propenyl>thio>-1-methyl-1H-imidazole 
• 80317-49-3 4-chloro-α-<1-methyl-3-(tetrahydro-2H-pyran-2-yl)-1-propenyl>benzenemethanol 
• 80317-39-1 (E)-2-<<3-(4-chlorophenyl)-2-methyl-2-propenyl>thio>-1-methyl-1H-imidazole 
• 80317-54-0 (E)-1-(4-chlorophenyl)-2-methyl-4-(tetrahydro-2H-pyran-2-yl)-2-buten-1-one 
• 80317-47-1 4-chloro-α-(1-methyl-1-propenyl)benzenemethanol 
• 56790-89-7 (E)-1-(4-chlorophenyl)-2-methyl-2-buten-1-one 

Relevant academic research and scientific papers

Synthesis of (E)-1-Aryl-2-methyl-3-alkyl-2-propen-1-ones via Allylic Sulfoxide-Sulfenate Ester Rearrangements

A synthon for vinyl anion 2 has been designed as the cornerstone for a versatile synthesis of (E)-1-aryl-2-methyl-3-alkyl-2-propen-1-ones (1).The choice of the allylic sulfoxide-sulfenate ester rearrangement as a synthesis conduit leads to formation of the desired E isomers stereoselectively.Attempted tetrahydropyran ring opening of enone 7c was not successful.