80323-31-5Relevant academic research and scientific papers
InCl3-catalyzed synthesis of 1,2-dimetallic compounds by direct insertion of aluminum or zinc powder
Bluemke, Tobias D.,Klatt, Thomas,Koszinowski, Konrad,Knochel, Paul
, p. 9926 - 9930 (2012)
In-sertion of metal: Catalytic amounts of InCl3 allow the insertion of aluminum and zinc into aromatic 1,2-dibromides or 1,2-bromotriflates (see scheme). These 1,2-dimetallic species can undergo Cu or Pd-catalyzed acylations, allylations, or cross-couplings. Copyright
Synthesis of 1,2-dimetallic compounds via direct insertion of zinc powder in the presence of InCl3: Synthesis of ortho-bis-functionalized aromatics
Klatt, Thomas,Blümke, Tobias D.,Ganiek, Maximilian A.,Knochel, Paul
supporting information, p. 290 - 294 (2014/02/14)
A variety of functionalized 1,2-dizinc reagents can be prepared by an indium-catalyzed insertion of zinc powder into aromatic 1,2-dibromides or 1-bromo-2-triflates. These 1,2-dimetallics undergo Cu- or Pd-catalyzed acylations, allylations, or cross couplings. Georg Thieme Verlag KG Stuttgart · New York.
