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(Fe(14ane)(BzNC)2)(PF6)2 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

80327-25-9

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80327-25-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 80327-25-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,0,3,2 and 7 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 80327-25:
(7*8)+(6*0)+(5*3)+(4*2)+(3*7)+(2*2)+(1*5)=109
109 % 10 = 9
So 80327-25-9 is a valid CAS Registry Number.

80327-25-9Downstream Products

80327-25-9Relevant academic research and scientific papers

Effects of spin change and unsaturation in the axial ligation of carbon monoxide and benzyl isocyanide to iron(II) macrocycles 14ane, 15ane, and TIM

Stynes, Dennis V.,Hui, Yat Sun,Chew, Vivien

, p. 1222 - 1225 (2008/10/08)

Reversible coordination of carbon monoxide to low-spin Fe(14ane)(CH3CN)22+ and high-spin Fe(15ane)(CH3CN)22+ is reported. A 2000-fold increase in CO lability and P1/2 for CO binding in the 15ane system is attributed to a synergistic combination of spin change and relief of macrocycle ring strain in the dissociation of CO. Benzyl isocyanide (BzNC) complexes of Fe(14ane) and Fe(TIM) are reported. Kinetic data for the reaction Fe(14ane)(CH3CN)(BzNC)2+ + BzNC → Fe(14ane)(BzNC)(BzNC)2+ + CH3CN are consistent with a dissociative mechanism involving a nondiscriminating reactive five-coordinate intermediate.

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