803731-35-3

Upstream product

• 1073-13-8 4,4-dimethylcyclohexenone 
• 768-33-2 phenyldimethylsilyl chloride 
• 91076-08-3 bis(dimethylphenylsilyl)zinc 

Downstream Products

• 908255-81-2 C₄₄H₆₀O₅S₄Si 
• 908255-90-3 (3S,5S,9S,10R,13R,17R)-3-(Dimethyl-phenyl-silanyl)-10-formyl-17-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-4,4,13-trimethyl-1,7-dioxo-2,3,4,5,6,7,9,10,11,12,13,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthrene-6-carboxylic acid allyl ester 
• 908255-80-1 (1S,3S,5S,9R,10R,13R,17R)-3-(Dimethyl-phenyl-silanyl)-1-hydroxy-10-hydroxymethyl-17-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-4,4,13-trimethyl-1,2,3,4,5,6,9,10,11,12,13,15,16,17-tetradecahydro-cyclopenta[a]phenanthren-7-one 
• 908255-79-8 (3S,5S,9S,10R,13R,17R)-3-(Dimethyl-phenyl-silanyl)-17-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-4,4,13-trimethyl-1,7-dioxo-1,2,3,4,5,6,7,9,11,12,13,15,16,17-tetradecahydro-cyclopenta[a]phenanthrene-10-carbaldehyde 
• 908255-87-8 (3S,5S,9S,10R,13R,17S)-17-Cyano-3-(dimethyl-phenyl-silanyl)-10-formyl-4,4,13-trimethyl-1,7-dioxo-2,3,4,5,6,7,9,10,11,12,13,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthrene-6-carboxylic acid allyl ester 
• 908255-88-9 Dithiocarbonic acid O-[(3S,5S,9S,10R,13R,17S)-17-cyano-3-(dimethyl-phenyl-silanyl)-4,4,13-trimethyl-1,7-dioxo-1,2,3,4,5,6,7,9,11,12,13,15,16,17-tetradecahydro-cyclopenta[a]phenanthren-10-ylmethyl] ester S-methyl ester 
• 908255-67-4 (3S,5S,9S,10R,13R,17S)-3-(Dimethyl-phenyl-silanyl)-10-hydroxymethyl-4,4,13-trimethyl-1,7-dioxo-2,3,4,5,6,7,9,10,11,12,13,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthrene-17-carbonitrile 
• 908255-66-3 (3S,5S,9S,10R,13R,17S)-3-(Dimethyl-phenyl-silanyl)-10-formyl-4,4,13-trimethyl-1,7-dioxo-2,3,4,5,6,7,9,10,11,12,13,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthrene-17-carbonitrile 
• 908255-86-7 (S)-4-(Dimethyl-phenyl-silanyl)-5,5-dimethyl-2-oxo-1-phenylselanyl-cyclohexanecarbaldehyde 
• 908255-64-1 (S)-4-(Dimethyl-phenyl-silanyl)-5,5-dimethyl-2-oxo-cyclohexanecarbaldehyde 
• 908255-65-2 (S)-4-(Dimethyl-phenyl-silanyl)-3,3-dimethyl-6-oxo-cyclohex-1-enecarbaldehyde 
• 908255-62-9 (1S,3S)-3-(Dimethyl-phenyl-silanyl)-4,4-dimethyl-cyclohexanol 
• 908255-63-0 (S)-3-(Dimethyl-phenyl-silanyl)-4,4-dimethyl-cyclohexanone 

Relevant academic research and scientific papers

Copper-catalyzed conjugate addition of a bis(triorganosilyl) zinc and a methyl(triorganosilyl) magnesium

A practical copper-catalyzed conjugate silylation of α,β- unsaturated carbonyl compounds 4 utilizing bis(triorganosilyl) zinc reagent 3 is described. Moreover, mixed methyl(triorganosilyl) magnesium 7 also transfers its silyl ligand to simple enones 4 und

Copper-free and copper-promoted conjugate addition reactions of bis(triorganosilyl) zincs and tris(triorganosilyl) zincates

In the course of our investigations directed towards an asymmetric copper-catalyzed silyl transfer from bis(triorganosilyl) zincs onto α,β-unsaturated carbonyl compounds, the presence of Lewis acidic lithium cations and the uncatalyzed background reaction