80379-74-4Relevant academic research and scientific papers
TRANSFORMATIONS OF 1,3-DIOXACYCLANES BY THE ACTION OF THE Fe(II) + H2O2 + Fe(III) SYSTEM
Trifonova, V.N.,Zorin, V.V.,Zlot-skii, S.S.,Rakhmankulov, D.L.
, p. 909 - 912 (2007/10/02)
The reaction of 1,3-dioxacyclanes with the Fe(II) + H2O2 + Fe(III) system in an aqueous medium leads to the formation of glycol monoesters, while the reaction in acetic acid leads to the formation of glycol diesters.The reaction takes place through the formation and one-electron oxidation of 1,3-dioxa-2-cycloalkyl radicals.If the ring is increased, the yield of the esters and the relative reactivity of the 1,3-dioxacyclanes are reduced. 2-Methyl-1,3-dioxacyclanes are more reactive than the corresponding formals.In the reaction of 1,3-dioxacyclanes with the Fe(II) + H2O2 + Fe(III) system in aqueous acetic acid a mixture of the monoesters and diesters is formed, and the ratios of their concentrations depends linearly on the ratio of the concentrations of water and acetic acid.
