80385-43-9

Basic information

• Product Name: Acetyl chloride, cyclohexylidene-
• CAS NO: 80385-43-9
• Molecular Formula: C8H11ClO
• Molecular Weight: 158.628
• Mol File: 80385-43-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Acetyl chloride, cyclohexylidene-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetyl chloride, cyclohexylidene-(80385-43-9)
• EPA Substance Registry System: Acetyl chloride, cyclohexylidene-(80385-43-9)

Safety Data

• Hazardous Substances Data: 80385-43-9(Hazardous Substances Data)

Upstream product

• 1552-91-6 cyclohexylideneacetic acid 
• 108-94-1 cyclohexanone 
• 7719-09-7 thionyl chloride 
• 14399-63-4 2-(1-hydroxycyclohexyl)acetic acid 
• 1552-92-7 ethyl cyclohexylideneacetate 

Downstream Products

• 65378-67-8 N,N-dimethylcyclohexylideneacetamide 
• 1017-23-8 2-(cyclohex-1-en-1-yl)-1-phenylethan-1-one 
• 67986-39-4 (cyclohexylideneacetyl)-o-toluidide 
• 377774-20-4 1-cyclohexylidene-butan-2-one 
• 186027-47-4 1-Cyclohexylidene-3-phenyl-propan-2-one 
• 219702-82-6 1-Cyclohexylidene-3-furan-3-yl-propan-2-one 
• 219702-93-9 1-Cyclohexylidene-3-thiophen-3-yl-propan-2-one 
• 186027-53-2 3-Cyclohexylidene-1-diazo-1-phenyl-propan-2-one 
• 186027-55-4 3-Cyclohexylidene-1-diazo-1-furan-3-yl-propan-2-one 
• 186027-54-3 3-Cyclohexylidene-1-diazo-1-thiophen-3-yl-propan-2-one 
• 874-68-0 1-cyclohexylidene-2-propanone 
• 1552-92-7 ethyl cyclohexylideneacetate 

Relevant articles and documents

INTRAMOLECULAR RING CLOSURE OF α,β-UNSATURATED 3-ACYLINDOLES

A number of unsaturated 3-acylindoles were prepared and annulated ( with HCl or NaCl-AlCl3 ) to 3,4-dihydrocyclopentindol-1(2H)-ones or 1,2,3,9-tetrahydro-4H-carbazol-4-ones depending on the structure of the substrate and/or the reaction conditions.

Pd-Catalyzed α-Selective C-H Functionalization of Olefins: En Route to 4-Imino-β-Lactams

Pd-catalyzed α-olefinic C-H activation of simple α,β-unsaturated olefins has been developed. 4-imino-β-lactam derivatives were readily synthesized via activation of α-olefinic C-H bonds with excellent cis stereoselectivity. A wide range of heterocycles at the β-position are compatible with this reaction. The product of 4-imino-β-lactam derivatives can be readily converted to 2-aminoquinoline which exists extensively in pharmaceutical drugs and natural products.

Thermal Conversion of Phorone into Isophorone via (Trimethylsilyl)oxyhexatriene (SOH) Cyclization

Heating of 3-Z-4-(trimethylsilyl)oxy-2,6-dimethylhepta-1,3,5-triene, readily available from phorone (LDA; TMSCl), at 220 deg C caused isomerization and cyclization to afford isophorone after deprotection.