80387-68-4

Basic information

• Product Name: 2-methylindole-3-carboxaldehyde 2,6-dimethylphenylhydrazone
• Synonyms: 2-methylindole-3-carboxaldehyde 2,6-dimethylphenylhydrazone
• CAS NO: 80387-68-4
• Molecular Weight: 277.369
• Mol File: 80387-68-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-methylindole-3-carboxaldehyde 2,6-dimethylphenylhydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methylindole-3-carboxaldehyde 2,6-dimethylphenylhydrazone(80387-68-4)
• EPA Substance Registry System: 2-methylindole-3-carboxaldehyde 2,6-dimethylphenylhydrazone(80387-68-4)

Safety Data

• Hazardous Substances Data: 80387-68-4(Hazardous Substances Data)

Upstream product

• 5416-80-8 2-methyl-1H-indole-3-carbaldehyde 
• 603-77-0 (2,6-dimethylphenyl)hydrazine 

Downstream Products

• 54827-17-7 3,3',5,5'-tetramethylbenzidine 
• 80387-72-0 3-(4-amino-3,5-dimethylphenyl)-2-methylindole 
• 87-62-7 2,6-dimethylaniline 
• 80387-73-1 3-(3,5-dimethylphenyl)-2-methylindole 

Relevant articles and documents

New Rearrangements of Arylhydrazones in Polyphosphoric Acid: Extension to the Thiophene and Indole Series. 5

The behavior toward polyphosphoric acid of arylhydrazones of a few heterocyclic carbonyl compounds of the thiophene and indole series is described.The phenylhydrazone and 2,6-dimethylphenylhydrazone of ethyl α-thienylglyoxylate gave ethyl 4- and 5-(4-aminoaryl)-α-thienylglyoxylate, arising from two different sigmatropic rearrangements.The N,3,5-trimethylphenylhydrazone of 2-methylindole-3-carboxaldehyde afforded the 4--2-methylindole-3-carboxaldehyde resulting from a sigmatropic rearrangement, while the 2,6-dimethylphenylhydrazone of the same carbonyl compound unexpectedly gave the 3-(4-amino-3,5-dimethylphenyl)-2-methylindole-3-carboxaldehyde generated through a sigmatropic reaction.Chemical evidences are given for the assigned structures.