80399-29-7Relevant academic research and scientific papers
Efficient construction of the clerodane decalin core by an asymmetric Morita-Baylis-Hillman reaction/Lewis acid promoted annulation strategy
Rodgen, Stacy A.,Schaus, Scott E.
, p. 4929 - 4932 (2007/10/03)
(Chemical Equation Presented) Linking rings: A general route toward the clerodane diterpene core using an asymmetric Morita-Baylis-Hillman (MBH)/ Lewis acid mediated ring-annulation process has been developed. The scope of the asymmetric Bronsted acid cat
A regiodefined synthesis of α-trimethylsilyl ketones catalyzed by rhodium(I) hydride complex
Sato, Susumu,Matsuda, Isamu,Izumi, Yusuke
, p. 71 - 88 (2007/10/02)
Regiodefined synthesis of α-trimethylsilyl ketones is attained by one of three different routes: isomerization of β-trimethylsilyl allyl alcohols (route A), isomerization of β'-trimethylsilyl allyl alcohols (route B), and dehydrogenation of β-trimethylsil
ENE-REACTIVITE D'ALLYLSILANES: FONCTIONNALISATION ET REGIOCHIMIE
Dubac, J.,Laporterie, A.,Iloughmane, H.,Pillot, J. P.,Deleris, G.,Dunogues, J.
, p. 149 - 162 (2007/10/02)
The hydroperoxidation of various allylsilanes by singlet oxygen has been studied.The regioselectivity of this reaction compared to those of ethyl azodicarboxylate and 4-phenyl-1,2,4-triazoline-3,5-dione, is discussed.Mechanisms are considered in the general field of the ene reaction applied to allylic organometallic Group IVB compounds.The structures of the new products (alcohols, urazoles, hydrazines) have been determined, directly or after transformations, by NMR spectroscopy.
