80401-17-8Relevant academic research and scientific papers
Synthesis of E-Vinylsilanes from Olefins with Vicinal Silyl and Stannyl Substituents
Mori, Miwako,Watanabe, Naoshi,Kaneta, Naotake,Shibasaki, Masakatsu
, p. 1615 - 1618 (2007/10/02)
E-Vinylsilanes were synthesized regioselectively from olefins with vicinal silyl and stannyl substituents, prepared from the corresponding terminal alkynes, by destannylation with HI.
SYNTHESIS OF VINYLSILANES BY PALLADIUM-CATALYZED REACTION OF TRIMETHYLSILYLALLYL ACETATES WITH NUCLEOPHILES
Hirao, Toshikazu,Enda, Jun,Ohshiro, Yoshiki,Agawa, Toshio
, p. 3079 - 3080 (2007/10/02)
Treatment of 1-trimethylsilylallyl and 3-trimethylsilylallyl acetates with nucleophiles (active methylene compounds and enamines) in the presence of a catalytic amount of Pd(PPh3)4 affords vinylsilane derivatives selectively.
