80403-07-2Relevant academic research and scientific papers
UNUSUAL RING CLEAVAGE REACTIONS OF 2-SUBSTITUTED 1,3-DITHIANES. ACCESS TO 2-ALKYLTHIOVINYLSILANES.
Hase, T. A.,Lahtinen, L.
, p. 3285 - 3288 (1981)
Two new cleavage reactions, under carbanion forming conditions, of the 1,3-dithiane ring system are reported.
SILICON MIGRATION AND RING CLEAVAGE REACTIONS OF 2-ALKYL-2-TRIMETHYLSILYLMETHYL-1,3-DITHIANES
Hase, Tapio A.,Lahtinen, Leila
, p. 9 - 16 (2007/10/02)
The synthesis and ring cleavage reactions of 2-alkyl-2-trimethylsilylmethyl-1,3-dithianes are described.The cleavages lead to 2-alkylthio-1-vinylsilanes and, via silicon migration, to 2--1-alkenes.
