80408-41-9Relevant academic research and scientific papers
ORGANOBORON COMPOUNDS. CDXIV. HOMOLOGATION OF 3-METHOXY-7-METHYL-3-BORABICYCLONONANE AND 3-METHOXY-7-METHOXYMETHYL-3-BORABICYCLONON-6-ENE USING α-HALOALKYLLITHIUM COMPOUNDS. SYNTHESIS OF 3-BORABICYCLODECANE AND 3-BORABICYCLODEC-7(8)-ENE DERIVATIVES
Gurskii, M. E.,Baranin, S. V.,Mikhailov, B. M.
, p. 9 - 16 (2007/10/02)
3-Methoxy-7-methyl-3-borabicyclononane (I) and 3-methoxy-7-methoxymethyl-3-borabicyclonon-6-ene (X) react with α-halomethyllithium compounds at decane and a mixture of 3-methoxy-8-methoxymethyl-3-borabicyclodec-7-ene and 3-methoxy-8-methoxymethyl-3-borabicyclodec-8-ene.A similar reaction of I or X with α-bromomethyllithium leads to the corresponding endo-4- and exo-4-methyl derivatives of 3-borabicyclodecane and 3-borabicyclodec-7(8)-ene.
