80411-31-0Relevant academic research and scientific papers
Preparation, Isomerization, and Reactions of Hydride Complexes of Ruthenium(II)
Bray, Joanne M.,Mawby, Roger J.
, p. 2989 - 2994 (2007/10/02)
Hydride complexes 2> (X = H or Cl, L = PMe2Ph or AsMe2Ph) and their deuteride analogues have been prepared.The complex exists in solution as an equilibrium mixture of isomers.The dideuteride exchanges with H2 in solution: no is formed, suggesting that exchange occurs via .Exchange also occurs with ethene and propene: here is observed.Ethene is hydrogenated by 2>, with formation of ethane and complexes 2>, which are reconverted to 2> by H2.The terminal alkenes 1-hexene and 3-phenylpropene are isomerized by 2>: for L = AsMe2Ph, a little hydrogenation of 3-phenylpropene also occurs.
Patterns of Nucleophilic Attack on Ethene Complexes of Ruthenium(II)
Stephenson, Martin,Mawby, Roger J.
, p. 2112 - 2118 (2007/10/02)
Although reaction of with the nucleophile PMe2Ph at 308 K simply results in substitution of the ethene ligand, studies at lower temperatures reveal that the kinetically favoured product is the cation Ru(CO)(CH2CH2PMe2Ph)Cl(PM
