80420-24-2Relevant academic research and scientific papers
GOLD(I) AND PLATINUM(II) AZOLATES AS LIGANDS IN CATIONIC RHODIUM(I) COMPLEXES
Uson, R.,Oro, L. A.,Ciriano, M. A.,Pinillos, M. T.,Cabeza, J. A.
, p. 249 - 256 (2007/10/02)
Several cationic heterometallic rhodium complexes have been obtained by using the complexes ImAuPPh3 or (az)2Pt(dpe) (az=imidazolate (Im) or pyrazolate (Pz) anions) as ligands.Attempts to prepare rhodium(I)-gold(I) derivatives containing pyrazolate-bridging ligands proved unsuccessful, rearrangements giving the complexes 2 and ClO4, ClO4 or AuClPPh3 as end-products.
