804500-77-4

Basic information

• Product Name: 1(2H)-Pyridinecarboxylic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3,6-dihydro-, phenylmethyl ester, (3R)-
• CAS NO: 804500-77-4
• Molecular Formula: C29H33NO3Si
• Molecular Weight: 471.671
• Mol File: 804500-77-4.mol

Chemical Properties

• CAS DataBase Reference: 1(2H)-Pyridinecarboxylic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3,6-dihydro-, phenylmethyl ester, (3R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1(2H)-Pyridinecarboxylic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3,6-dihydro-, phenylmethyl ester, (3R)-(804500-77-4)
• EPA Substance Registry System: 1(2H)-Pyridinecarboxylic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3,6-dihydro-, phenylmethyl ester, (3R)-(804500-77-4)

Safety Data

• Hazardous Substances Data: 804500-77-4(Hazardous Substances Data)

Upstream product

• 501-53-1 benzyl chloroformate 
• 804500-74-1 benzyl N-allyl-N-[(2R,3E)-2-(t-butyldiphenylsilyl)oxy-pent-3-en-1-yl]carbamate 

Downstream Products

• 174956-48-0 benzyl (3R)-3-hydroxy-3,6-dihydropyridine-1(2H)-carboxylate 

Relevant articles and documents

Conversion of chiral unsaturated cyanohydrins into chiral carba- and heterocycles via ring-closing metathesis

Aliphatic unsaturated cyanohydrins 1-3 served as starting materials in the synthesis of a set of new chiral unsaturated cyclic 1,2-ethanolamines. Combining a Grignard addition-NaBH4 reduction sequence with a ring-closing metathesis afforded uns