804533-76-4Relevant academic research and scientific papers
Crystal and molecular structures of the pentafluorosulfanyl compounds, SF5X (X = -NC, -CN, -NCO, -NCS and -NCCl2) by X-ray diffraction at low temperature
Buschmann, Juergen,Lentz, Dieter,Luger, Peter,Perpetuo, Genivaldo,Preugschat, Dagmar,Thrasher, Joseph S.,Willner, Helge,Woelk, Hans-Joerg
, p. 1136 - 1142 (2004)
A new method for the synthesis of the unstable pentafluorosulfanyl isocyanide from N-(pentafluorosulfanyl)(dichloromethanimine) was developed, thereby allowing for the study of its spectroscopic data. The structure of pentafluorosulfanyl isocyanide was determined by X-ray crystallography at 113 K. The molecule possesses an almost linear S-N-C arrangement and an unexpectedly long S-N bond. In addition, the structures of pentafluorosulfanyl cyanide, pentafluorosulfanyl isocyanate, pentafluorosulfanyl isothiocyanate, and N-(pentafluorosulfanyl)(dichloro)methanimine were determined by single crystal X-ray crystallography at low temperatures.
