80476-49-9Relevant academic research and scientific papers
Disilapropellanes: Synthesis and structure
Zoch, Hans-Georg,Szeimies, Guenter,Butkowskyj, Theodora,Meerssche, Maurice Van,Germain, Gabriel,Declercq, Jean-Paul
, p. 3896 - 3905 (2007/10/02)
The reaction of tricyclo2,7>hept-1-yllithium with dichlorosilanes or tetrachlorosilane afforded silyl-substituted tricyclo2,7>heptane derivatives 2, 4 which, after metalation of the bicyclobutane bridgehead positions, could be cyclized with dichlorosilanes to give disilapropellanes 5, 6.The structure of 5a has been determined by X-ray analysis.
