80521-49-9Relevant academic research and scientific papers
Microwave-assisted synthesis of 2-substituted 4-biarylyl-1,3-thiazoles by carbon-carbon cross-coupling in water
Dawood, Kamal M.,El-Deftar, Moteaa M.
scheme or table, p. 1030 - 1038 (2010/06/16)
Suzuki-Miyaura and Heck-Mizoroki C-C cross-coupling reactions of 4-(halophenyl)-1,3-thiazoles with aryl(hetaryl)boronic acids or olefins, respectively, were investigated by using a catalytically active benzimidazole-based palladium(II) complex under both thermal and microwave heating conditions in water. The factors affecting the optimization of such reactions were evaluated.
Intramolecular Nitrogen-Phosphorus Interactions of Phosphate Esters
Bushey, Dean F.,Johnson, Brenda F.,Huang, Jamin
, p. 2091 - 2095 (2007/10/02)
Four different classes of phosphate esters derived from enols, phenols, carbinols, and oximes have been shown to undergo intramolecular rearrangements assisted by a neighboring nitrogen.The unexpected products from these rearrangements have been characterized by spectral methods, especially 13C NMR.Rearrangements involving the O-ethyl S-propyl thiophosphate group have led to particularly interesting results.
