80522-45-8Relevant academic research and scientific papers
Pd(OH)2/C-mediated selective oxidation of silyl enol ethers by tert-butylhydroperoxide, a useful method for the conversion of ketones to α,β-enones or β-Silyloxy-α,β-enones
Yu, Jin-Quan,Wu, Hai-Chen,Corey
, p. 1415 - 1417 (2005)
(Chemical Equation Presented) Pd(OH)2-catalyzed oxidation of silyl enol ethers by t-BuOOH gives either β-silyloxy-α,β-enones or α,β-enones in good yields depending on the base used.
Oxidative addition of azide anion to triisopropylsilyl enol ethers: Synthesis of α-azido ketones and 2-amino(methoxycarbonyl)alk-2-en-1-ones
Magnus, Philip,Barth, Lisa
, p. 11075 - 11086 (2007/10/02)
Treatment of triisopropylsilyl enol ethers with ceric ammonium nitrate/sodium azide at -20°C in acetonitrile gives α-azido ketones in average to good yields (50-80%). Subsequent conversion of the α-azido ketones into 2-amino(methoxycarbonyl)cycloalk-2-en-1-ones is described.
STUDIES WITH TRIALKYLSILYLTRIFLATES: NEW SYNTHESES AND APPLICATIONS
Corey, E. J.,Cho, Hidetsura,Ruecker, Christoph,Hua, Duy H.
, p. 3455 - 3458 (2007/10/02)
Syntheses and applications are described for three useful reagents for silylation of unreactive substrates, tert-butyldimethylsilyl, triisopropylsilyl, and octadecyldimethylsilyl triflate.
