80522-45-8

Basic information

• Product Name: Silane, (1-cyclopenten-1-yloxy)tris(1-methylethyl)-
• CAS NO: 80522-45-8
• Molecular Formula: C14H28OSi
• Molecular Weight: 240.461
• Mol File: 80522-45-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, (1-cyclopenten-1-yloxy)tris(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1-cyclopenten-1-yloxy)tris(1-methylethyl)-(80522-45-8)
• EPA Substance Registry System: Silane, (1-cyclopenten-1-yloxy)tris(1-methylethyl)-(80522-45-8)

Safety Data

• Hazardous Substances Data: 80522-45-8(Hazardous Substances Data)

Upstream product

• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 
• 120-92-3 cyclopentanone 

Downstream Products

• 1379829-53-4 C₄₅H₆₆O₅Si 
• 930-30-3 cyclopent-2-enone 

Relevant articles and documents

Pd(OH)2/C-mediated selective oxidation of silyl enol ethers by tert-butylhydroperoxide, a useful method for the conversion of ketones to α,β-enones or β-Silyloxy-α,β-enones

(Chemical Equation Presented) Pd(OH)2-catalyzed oxidation of silyl enol ethers by t-BuOOH gives either β-silyloxy-α,β-enones or α,β-enones in good yields depending on the base used.

STUDIES WITH TRIALKYLSILYLTRIFLATES: NEW SYNTHESES AND APPLICATIONS

Syntheses and applications are described for three useful reagents for silylation of unreactive substrates, tert-butyldimethylsilyl, triisopropylsilyl, and octadecyldimethylsilyl triflate.