80522-47-0

Basic information

• Product Name: Silane, [[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]oxy]tris(1-methylethyl)-
• CAS NO: 80522-47-0
• Molecular Formula: C19H38OSi
• Molecular Weight: 310.596
• Mol File: 80522-47-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Silane, [[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]oxy]tris(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]oxy]tris(1-methylethyl)-(80522-47-0)
• EPA Substance Registry System: Silane, [[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]oxy]tris(1-methylethyl)-(80522-47-0)

Safety Data

• Hazardous Substances Data: 80522-47-0(Hazardous Substances Data)

Upstream product

• 6485-79-6 chlorotriisopropylsilane 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 94017-66-0 (2S,4S)-4-tert-Butyl-2-triisopropylsilanyl-cyclohexanone 

Downstream Products

• 32741-89-2 5-(tert-butyl)azepan-2-one 
• 937-07-5 4-tert-butylcyclohex-2-enone 
• 94017-66-0 (2S,4S)-4-tert-Butyl-2-triisopropylsilanyl-cyclohexanone 
• 94017-66-0 (2S,4R)-4-tert-Butyl-2-triisopropylsilanyl-cyclohexanone 

Relevant articles and documents

Intermolecular C-O Bond Formation with Alkoxyl Radicals: Photoredox-Catalyzed α-Alkoxylation of Carbonyl Compounds

Due to the high reactivity of alkoxyl (RO·) radicals and their propensity to easily undergo β-scission or Hydrogen Atom Transfer (HAT) reactions, intermolecular alkoxylations involving RO· radicals are barely described. We report herein for the first time the efficient intermolecular trapping of alkoxyl radicals by silyl enol ethers. This photoredox-mediated protocol enables the introduction of both structurally simple and more complex alkoxy groups into a wide range of ketones and amides.

Pd(OH)2/C-mediated selective oxidation of silyl enol ethers by tert-butylhydroperoxide, a useful method for the conversion of ketones to α,β-enones or β-Silyloxy-α,β-enones

(Chemical Equation Presented) Pd(OH)2-catalyzed oxidation of silyl enol ethers by t-BuOOH gives either β-silyloxy-α,β-enones or α,β-enones in good yields depending on the base used.

THE 1,3 OC SILYL REARRANGEMENT OF SILYL ENOL ETHER ANIONS - SYNTHESIS OF α-SILYL KETONES

Silyl enol ethers with sterically hindered silyl groups are transformed into the corresponding α-silyl ketones by treatment with n-butyllithium/potassium tert-butylate.