80522-97-0Relevant academic research and scientific papers
UNPRECEDENTED REARRANGEMENTS VIA ALLENES AS ?-PARTICIPANTS IN α-ACYLIMINIUM ION CYCLISATIONS
Nossin, Peter M. M.,Speckamp, W. Nico
, p. 3289 - 3292 (1981)
Upon HCOOH reaction of ethoxylactams 1a-1d the terminally unsubstituted allenes 1a and 1d underwent a sigmatropic rearrangement.The dimethyl allenes 1b and 1c afforded only products from an α-acyliminium ion cyclisation.
