80532-34-9

Upstream product

• 65398-92-7 p-(1,2-dimethyl-1-nitropropyl)nitrobenzene 
• 80516-32-1 2-Methyl-propionaldehyde O-[1,2-dimethyl-1-(4-nitro-phenyl)-propyl]-oxime 
• 80516-30-9 tetrabutylammonium 2-methyl-1-nitro-1-propanide 
• 3958-63-2 lithium 2-nitropropane 
• 65398-95-0 Tetra-n-butyl-ammonium 2-nitropropanate 
• 28735-55-9 lithium 1-nitroethan-1-ide 

Relevant academic research and scientific papers

Regiochemistry of the Association Step in SRN1 Reactions; Kinetically Controlled Coupling of aci-Nitronate Ions and p-Nitrobenzylic Radicals

The regiochemistry of the coupling between p-nitrobenzylic radicals and aci-nitronate ions in the association step of SRN1 reactions is shown to be dependent on steric factors.Branching at the carbon which is α to the reaction site causes a shi

The Correlation of Regiochemistry with Structure in the SRN1 Reaction of aci-Nitronates with p-Nitrobenzylic Substrates

The rate and regiochemistry of the SRN1 reactions of aci-nitronates with p-nitrobenzylic substrates are profoundly affected by branching at the positions adjacent to the reaction sites (Cβ).Definitive rules which predict whether C-alkylation will occur in the association step involving p-nitrobenzylic radicals and aci-nitronate ions are formulated. β-Branching causes O-alkylation or reductive processes to increase.In some cases no recognizable product formation results.Benzylic alcohols, p-nitrophenyl alkyl ketones and/or their oximes, and p-nitrophenol are among the products which result from subsequent reactions of the O-alkylation products, aci-nitronic esters of benzylic alcohols.