80544-70-3

Upstream product

• 591-31-1 3-methoxy-benzaldehyde 
• 6768-23-6 diethyl-2-(4-methoxybenzylidene)malonate 
• 80534-79-8 diethyl malonyl-1 metamethoxyphenyl-1 butene-3 

Downstream Products

• 80535-08-6 N-methyl epoxy-5,6 metamethoxyphenyl-3 hexyl trifluoroacetamide 
• 80535-07-5 N-methyl metamethoxyphenyl-3 hexene-5 yl trifluoroacetamide 
• 62114-69-6 N-benzyl N-methyl metamethoxyphenyl-3 hexene-5 yl amine 
• 62114-68-5 N-allyl N-methyl metamethoxyphenyl-3 hexene-5 yl amine 
• 80544-67-8 hydroxy methyl-2 metamethoxyphenyl-4 piperidine 
• 80535-03-1 N-chloro N-methyl metamethoxyphenyl-3 hexene-5 yl amine 
• 80535-09-7 Ethyl-[3-(3-methoxy-phenyl)-hex-5-enyl]-methyl-amine 
• 62114-67-4 N,N-dimethyl metamethoxyphenyl-3 hexene-5 yl amine 
• 62114-63-0 N-methyl metamethoxyphenyl-3 hexene-5 yl amine 
• 80535-10-0 3-(3-Methoxy-phenyl)-hex-5-enoic acid methylamide 

Relevant academic research and scientific papers

SYNTHESE RADICALAIRE D'ANALGESIQUES POTENTIELS: ARYL-4 PIPERIDINES SUBSTITUEES EN 2 ET BENZOMORPHANES

The synthesis of a series of 3-aryl 5-hexenyl amines and the cyclisations of the corresponding N-chloroamines are described.When the ring closure results from the amino radical addition to the ethylenic double bond, 2-chloromethyl 4-phenyl piperidines are obtained.These compounds lead by intramolecular Friedel-Crafts reaction to varied substituted 6,7-benzomorphanes.When the phenyl ring is substituted with a methoxyl group, the cyclisation proceeds via homolytic aromatic substitution and 4-allyl tetrahydroquinolines are formed.