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Tris(trimethylsiloxo)-phenyliminovanadium(V) is a complex organometallic compound with the chemical formula [V(N=CPh)(SiMe3O)3]. It features a vanadium(V) center coordinated to a phenylimino ligand (N=CPh) and three trimethylsiloxo ligands (SiMe3O). tris(trimethylsiloxo)-phenyliminovanadium(V) is of interest in organometallic chemistry and catalysis due to its unique structure and potential applications in various chemical transformations. The phenyliminovanadium(V) moiety can act as a redox-active center, while the trimethylsiloxo groups provide steric bulk and influence the electronic properties of the complex. Research on such compounds can lead to the development of new catalysts and insights into the role of metal-ligand interactions in reactivity.

80545-63-7

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80545-63-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 80545-63-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,0,5,4 and 5 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 80545-63:
(7*8)+(6*0)+(5*5)+(4*4)+(3*5)+(2*6)+(1*3)=127
127 % 10 = 7
So 80545-63-7 is a valid CAS Registry Number.

80545-63-7Downstream Products

80545-63-7Relevant academic research and scientific papers

Synthesis and Properties of tert-Butyliminovanadium(V) Compounds tC4H9N=VX3 (X = Cl, RCOO)

Preuss, Fritz,Towae, Willi

, p. 1130 - 1135 (2007/10/02)

tC4H9N=V(OSiMe3)3 has been prepared by reaction of NH4VO3 with HNSiMe3(tC4H9).This compound is the starting material for the synthesis of C6H5N=V(OSiMe3)3 and tC4H9N=VCl3 by transamination with aniline or redistribution with VOCl3, respectively.The properties of the trichloride are studied by chemical reactions such as redistribution, complex formation and substitution with silver carboxylates.All compounds are monomeric in solution, probably containing a nitrogen vanadium triple bond.The structure of 2,2'-dipyridyl complexes tC4H9N=VX3*C10H8N2> (X = Cl, CH3COO) has been found to be octahedral with meridional arrangement of chloride or acetate ligands. - Key words: tert-Butyliminovanadium(V) Trichloride and Tricarboxylates, 1H NMR Spectra, IR Spectra

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