80583-63-7

Upstream product

• 14221-01-3 tetrakis(triphenylphosphine) palladium⁽⁰⁾ 
• 341-02-6 trityl tetrafluoroborate 

Downstream Products

• 80583-68-2 bis(1,10-phenanthroline)(triphenylphosphine)palladium(II) tetrafluoroborate-acetone (1/1) 
• 33680-09-0 bis(triphenylphosphine)(acetylacetonato)palladium(II) tetrafluoroborate-acetone (1/1) 

Relevant academic research and scientific papers

Dicationic tetrakis(triphenylphosphine)palladium(II) and tetrakis(triphenyl phosphite)palladium(II) complexes

The synthesis and properties of the cationic palladium(II) complexes are described. Dicationic [Pd(PPh3)4](X)2 (X = BF4-, PF6-) and [Pd(P(OPh)3)4](PF6)2 have been prepared by the reaction of Pd(PPh3)4 with CPh3X (X = BF4-, PF6-). A pentacoordinated Pd(II) complex of the heterocyclic ligand 1,10-phenanthroline, [Pd(1,10-phen)2(PPh3)](X)2) was obtained from the reaction of [Pd(PPh3)4](X)2 with 1,10-phen. Monocationic [Pd(CH3COCHCO-R)(PPh3)2](X) (R = Me, OMe) has been isolated from the reaction of Pd(PPh3)4 with CPh3X in the presence of acetylacetone or methyl acetoacetate. Likely structures and some features for these new complexes are proposed from 1H NMR and IR spectrometry.