80584-60-7Relevant academic research and scientific papers
Novel Aryl Substituted Silanes Part I: Synthesis and Characterization of Diaryl Silicon Dichlorides
Binder, Judith,Fischer, Roland C.,Flock, Michaela,Torvisco, Ana,Uhlig, Frank
, p. 1980 - 1994 (2015/12/12)
A series of novel and previously published silicon dichlorides, R2SiCl2 (R = benzyl, fluorenyl, p-tolyl p-n-butyl, p-biphenyl, m-tolyl, o-tolyl, 2,4-xylyl, 2,6-xylyl, p-biphenyl, 1-naphthyl, 9-anthracenyl), were synthesized and chara
Process for preparing cyclopentadienyl group-containing silicon compound or cyclopentadienyl group-containing germanium compound
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, (2008/06/13)
Disclosed is a process for preparing a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, comprising reacting (i) a lithium, sodium or potassium salt of a cyclopentadiene derivative with (ii) a silicon halide compound or a germanium halide compound in the presence of a cyanide or a thiocyanate. The cyanide or the thiocyanate is preferably a copper salt. According to the process of the invention, a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, which is very useful for the preparation of a metallocene complex catalyst component, can be prepared in a high yield for a short period of time.
