80587-41-3

Basic information

• Product Name: Ethanone, 1-(2-methyl-3-methylenecyclopropyl)-, trans- (9CI)
• Synonyms: Ethanone, 1-(2-methyl-3-methylenecyclopropyl)-, trans- (9CI)
• CAS NO: 80587-41-3
• Molecular Formula: C7H10O
• Molecular Weight: 110.1537
• Product Categories: ACETYLGROUP
• Mol File: 80587-41-3.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-(2-methyl-3-methylenecyclopropyl)-, trans- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(2-methyl-3-methylenecyclopropyl)-, trans- (9CI)(80587-41-3)
• EPA Substance Registry System: Ethanone, 1-(2-methyl-3-methylenecyclopropyl)-, trans- (9CI)(80587-41-3)

Safety Data

• Hazardous Substances Data: 80587-41-3(Hazardous Substances Data)

Upstream product

• 917-54-4 methyllithium 
• 36228-28-1 acide methyl-2 methylene-3 cyclopropanecarboxylique 1R*2R* 

Relevant articles and documents

Diastereoselectivite de la reduction des alkyl-2 alkylidene-3 cyclopropyl alkyl cetones. Addition de RLi sur les aldehydes α-cyclopropylideniques

The addition of RLi on trans 2-alkyl-3-methylene cyclopropane carboxaldehydes is not diastereoselective, while the reduction of trans (2-alkyl-3-alkylidene cyclopropyl) alkyl ketones shows for some compounds a high diastereoselectivity which may reach stereospecificity at low temperatures.This selectivity depends not only on the degree of substitution of the group fixed on the carbonyl but on the radical fixed in position 2 on the ring even though it shows a trans relation with the functional group.The relative configurations of secondary α-cyclopropylidene alcohols are determined from their ir and nmr data.