80606-53-7

Basic information

• Product Name: Ethanone, 1-pentacyclo[4.3.0.02,5.03,8.04,7]non-4-yl- (9CI)
• Synonyms: Ethanone, 1-pentacyclo[4.3.0.02,5.03,8.04,7]non-4-yl- (9CI)
• CAS NO: 80606-53-7
• Molecular Formula: C₁₁H₁₂O
• Molecular Weight: 160.21238
• Product Categories: ACETYLGROUP
• Mol File: 80606-53-7.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-pentacyclo[4.3.0.02,5.03,8.04,7]non-4-yl- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-pentacyclo[4.3.0.02,5.03,8.04,7]non-4-yl- (9CI)(80606-53-7)
• EPA Substance Registry System: Ethanone, 1-pentacyclo[4.3.0.02,5.03,8.04,7]non-4-yl- (9CI)(80606-53-7)

Safety Data

• Hazardous Substances Data: 80606-53-7(Hazardous Substances Data)

Upstream product

• 15844-05-0 Pentacyclo<4.3.0.0^2,5.0^3,8.0^4,7>nonane-4-carboxylic acid 
• 917-54-4 methyllithium 

Downstream Products

• 80605-83-0 4-Homocubylmethylketoxim-pikrat 
• 40317-63-3 4-Homocubancarbonsaure-methylester 
• 84790-10-3 4-Homocubylacetat 

Relevant articles and documents

Wanderungstendenzen cyclischer, polycyclischer und methylverzweigter Alkylreste bei der Beckmann-Umlagerung

The migration aptitudes of polycyclic bridgehead groups, cycloalkyl groups as well as of β-, γ- and δ-branched alkyl groups in the Chapman variant of the Beckmann rearrangement were determined.From these data it is concluded that at transition state 2 the migrating group is not resembling a planarised carbenium ion R+, but rather a pentacoordinated carbonium ion structure.Because only small geometrical changes occur in the migrating group vertical stabilisation of charge at transition state is believed to have significant influence on the migration aptitudes.