80615-38-9Relevant academic research and scientific papers
SYNTHESIS AND SUBSTITUENT EFFECT ON 31P NMR CHEMICAL SHIFT OF ORTHO-HYDROXYARYL DIALKYL PHOSPHINE OXIDES
Li, Shusen,Wang, Guoquan
, p. 119 - 129 (2007/10/02)
In this paper, the synthetic methods for the preparation of o-hydroxyaryl dialkyl phosphine oxides (1) are introduced.The title compounds with low bulky substituent are synthesized successfully by the reactions of Grignard reagents with diethyl o-hydroxya
Chemistry of the Podocarpaceae. LXI. The Rearrangement of Aryl Phosphates to ortho-Hydroxyaryl Phosphanates
Cambie, Richard C.,Palmer, Brian D.
, p. 827 - 837 (2007/10/02)
Treatment of methyl 12-(diethoxyphosphoryloxy)podocarpa-8,11,13-trien-19-oate (14) or its 13-bromo derivative (7) with butyllithium effects a rearrangement of the phosphate group to give methyl 13-diethoxyphosphoryl-12-hydroxypodocarpa-8,11,13-trien-19-oa
AN EFFICIENT SYNTHESIS OF 2-HYDROXYPHENYLPHOSPHONATES
Melvin, L. S.
, p. 3375 - 3376 (2007/10/02)
The high yield conversion of phenols into diethyl 2-hydroxyphenylphosphonates via base catalyzed rearrangement of diethyl phenyl phosphates has been achieved.
