80639-18-5

Basic information

• Product Name: (E)-1,4-hexadien-3-yl acetate
• Synonyms: (E)-1,4-hexadien-3-yl acetate
• CAS NO: 80639-18-5
• Molecular Weight: 140.182
• Mol File: 80639-18-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-1,4-hexadien-3-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1,4-hexadien-3-yl acetate(80639-18-5)
• EPA Substance Registry System: (E)-1,4-hexadien-3-yl acetate(80639-18-5)

Safety Data

• Hazardous Substances Data: 80639-18-5(Hazardous Substances Data)

Upstream product

• 1070-14-0 hexa-1,4-dien-3-ol 
• 108-24-7 acetic anhydride 
• 59095-52-2 hex-4-en-1-yn-3-ol 
• 91001-07-9 (E)-hexa-1,4-dien-3-ol 

Downstream Products

• 57006-69-6 (E,E)-sorbyl acetate 
• 1070-14-0 hexa-1,4-dien-3-ol 

Relevant articles and documents

Sequential catalytic isomerization and allylic substitution. Conversion of racemic branched allylic carbonates to enantioenriched allylic substitution products

A catalytic protocol for the conversion of readily accessible racemic, branched aromatic allylic esters to branched allylic amines, ethers, and alkyls has been developed. Palladium-catalyzed isomerization of branched allylic esters to terminal allylic esters, followed by sequential iridium-catalyzed allylic substitution, gave the branched allylic products in good yield with high regioisomeric and enantiomeric selectivity. Both electron-rich and electron-poor branched allylic esters gave products in >90% ee. High enantiomeric excesses were also observed for the products from the reactions of 2-thienyl acetates and dienyl carbonates. Copyright