80639-62-9

Usage

Chemical structure

A heterocyclic compound with a twelve-membered ring containing two oxygen atoms and two nitrogen atoms.

Substituents

Contains a sulfonyl group and phenylmethyl groups.

Applications

Potential uses in pharmaceuticals and agrochemicals.

Chelating agent

Can bind to metal ions.

Antibacterial and antifungal properties

Has potential as an antibacterial and antifungal agent.

Catalyst

May have uses as a catalyst in chemical processes.

Upstream product

• 72358-83-9 N,N-bis<2-(2-hydroxyethoxy)ethyl>-4-methylbenzenesulfonamide 
• 70-55-3 toluene-4-sulfonamide 
• 80639-61-8 6-<(4-methylphenyl)sulfonyl>-3,9-dioxa-6-aza-1,11-undecanediol bis(methanesulfonate) 
• 100-46-9 benzylamine 
• 80639-60-7 4-Methyl-N,N-bis-{2-[2-(tetrahydro-pyran-2-yloxy)-ethoxy]-ethyl}-benzenesulfonamide 

Downstream Products

• 96563-14-3 4-carbethoxy-10-<(4-methylphenyl)sulfonyl>-1,7-dioxa-4,10-diazacyclododecane 
• 96563-20-1 4,4'-(2-benzyl-1,3-propanediyl)bis(1,7-dioxa-4,10-diazacyclododecane) 
• 96563-18-7 4,4'-(2-benzyl-1,3-propanediyl)bis<10-<(4-methylphenyl)sulfonyl>-1,7-dioxa-4,10-diazacyclododecane> 
• 96563-17-6 4,4'-(2-hexadecyl-1,3-propanediyl)bis<10-<(4-methylphenyl)sulfonyl>-1,7-dioxa-4,10-diazacyclododecane> 
• 80639-63-0 N-benzyl-1,7-diaza-4,10-dioxacyclododecane 
• 96563-15-4 4-[(4-methylphenyl)sulfonyl]-1,7-dioxa-4,10-diazacyclododecane 
• 115942-17-1 12-benzyl-7,17,22,27-tetraoxa-1,4,10,14-tetraazatricyclo<12.5.5.5^4,10>nonacosane 
• 80639-64-1 7,7'-bis-benzyl-1,1'-ethylenebis(1,7-diaza-4,10-dioxacyclododecane) 

Relevant academic research and scientific papers

Lipophilic Cage Ligands Containing Two Tightly Connected 1,7-Dioxa-4,10-diazacyclododecane Rings: Synthesis and X-ray Structure of a Sodium Perchlorate Complex

Sodium perchlorate complexes 2 of lipophilic macrotricyclic receptors 1 were obtained in high yield by following a synthetic route in which sodium cation acts as the templating agent in the last step.Complexes with several inorganic salts were directly prepared from the free ligands 1, obtained by decomplexation of 2, or via anionic exchange from the complexes 2.Extraction data of alkali halides under two-phase conditions (H2O-CHCl3) with ligand 1a showed a cation extraction selectivity order Na+ >> K+ > Li+.Under liquid-liquid two-phase conditions, ligands 1 proved to be effective phase-transfer catalysts in hydroxide ion initiated carbanion formation from very weak carbon acids.The sodium complex 2a was crystallographically characterized.The sodium cation is in a nonsymmetric cubic environment of four oxygen (Na O 2.46 Angstroem) and four nitrogen (Na N 2.79 Angstroem) atoms.

Synthesis of a Cation Complexing Doubly N,N'-Bridged Bis-(1,7-dioxa-4,10-diazacyclododecane)

Two molecules of diaza-12-crown-4 can be linked by two ethylene bridges between nitrogen atoms in two controlled steps, the last of which needs Li cation as a template, although Na cation is most strongly complexed by the tricyclic cryptand-like product.