80642-54-2Relevant academic research and scientific papers
Synthesis and characterization of cationic iron vinylidene compounds. Formation of C-H, C-N, and C-P bonds and the X-ray crystal structure of [Fe(η-C5H5)(CO)(PPh3){C(PPh 3)=CH2}]+BF4-
Boland-Lussier, Barbara L.,Churchill, Melvyn Rowen,Hughes, Russell P.,Rheingold, Arnold L.
, p. 628 - 634 (2008/10/08)
The syntheses and spectroscopic characterization of the vinylidene complexes [Fe(η-C5H5|(CO)(L)[C=CH2) +BP4-[L = PPh3, R= Me, H; L = PMe2Ph, P(C6H11)3, R = H], from the acyl precursors [Fe-(ηC5H5)(CO)(L)[C(O)CHR2]] and trifluoromethane:sulfonic anhydride in thi presence of HBF4-Et2O, are described.
