80651-19-0Relevant academic research and scientific papers
USE OF ZIRCONIUM COMPLEXES AS CATALYSTS FOR LINEAR DIMERIZATION AND CODIMERIZATION OF CONJUGATED DIENES AND TRIENES
Dzhemilev, U. B.,Ibragimov, A. G.,Tolstikov, G. A.,Vostrikova, O. S.,Zelenova, L. M.
, p. 2066 - 2071 (2007/10/02)
The linear dimerization and codimerization of conjugated 1,3-dienes with various degrees of substitution in the presence of the catalytic system Zr(OBu)4-Ph3P-AlEt2Cl was investigated systematically.The possibility of obtaining polyenes with a given structure from 1,3-dienes and trienes was demonstrated.The most probable scheme for the formation of the dimers and codimers is proposed.
