80677-33-4Relevant academic research and scientific papers
Mechanisms in Electrophilic Reactions of Reactive Nitrogen Compounds with Phosphanes
Heesing, Albert,Steinkamp, Heinz
, p. 2854 - 2864 (2007/10/02)
Chiral phosphanes were used as nucleophiles in reactions with reactive nitrogen compounds to investigate the mechanisms by stereochemical means:a) Retention on phosphorus occurs in the amination with O-(mesitylsulfonyl)hydroxylamine consistent with a Ssu
MECHANISMEN BEI REAKTIONEN VON CHIRALEN PHOSPHANEN MIT ELEKTRONEGATIV-SUBSTITUIERTEN STICKSTOFFVERBINDUNGEN
Heesing, A.,Steinkamp, H.
, p. 3827 - 3828 (2007/10/02)
In the reaction of the chiral phosphane 1 with electronegative substituted nitrogen compounds both a SN (N) mechanism and nucleophilic attack on the nitrogen substituent occur depending on the nature of the nucleofuge.
