80679-26-1

Basic information

• Product Name: 2-(DIPHENYLPHOSPHINO)-1,3-BENZOTHIAZOLE
• Synonyms: 2-(DIPHENYLPHOSPHINO)-1,3-BENZOTHIAZOLE
• CAS NO: 80679-26-1
• Molecular Formula: C₁₉H₁₄NPS
• Molecular Weight: 319.36
• Mol File: 80679-26-1.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(DIPHENYLPHOSPHINO)-1,3-BENZOTHIAZOLE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(DIPHENYLPHOSPHINO)-1,3-BENZOTHIAZOLE(80679-26-1)
• EPA Substance Registry System: 2-(DIPHENYLPHOSPHINO)-1,3-BENZOTHIAZOLE(80679-26-1)

Safety Data

• Hazardous Substances Data: 80679-26-1(Hazardous Substances Data)

Upstream product

• 65567-06-8 lithium diphenylphosphide 
• 1079-66-9 chloro-diphenylphosphine 
• 720675-16-1 bbenzo[d]thiazol-2-yldiphenylphosphine oxide 
• 95-16-9 1,3-Benzothiazole 
• 32137-73-8 2-(trimethylsilyl)benzothiazole 

Downstream Products

• 1258796-19-8 [(2-(diphenylphosphino)benzo[d]thiazole)₃Cu₂I₂] 

Relevant articles and documents

Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides

A silver nitrate-mediated, efficient phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides was developed. This process provides a convenient route for the synthesis of a variety of 2-diarylphosphoryl benzothiazoles and thiazoles which are promising precursors of a series of hemilabile P,N-ligands with small bite angles. This journal is

(tmp)2Zn·2 MgCl2·2 LiCl: A chemoselective base for the directed zincation of sensitive arenes and heteroarenes

(Chemical Equation Presented) Positive zincing: A wide range of polyfunctional aryl and heteroaryl zinc reagents were efficiently prepared in THF by direct zincation using (tmp)2Zn·2 MgCl 2·2 LiCl (1), an exceptionally active base. Ester and cyano functions as well as aldehydes and nitro groups are tolerated. dba = dibenzylideneacetone, tmp = 2,2,6,6-tetramethylpiperidide.