80697-33-2Relevant academic research and scientific papers
Reductive Elimination of Acetonides, Cyclic Carbonates, or Cyclic Sulfites of γ,δ-Dihydroxy (E)-α,β-Unsaturated Esters: An Efficient Route to δ-Hydroxy-(E)-β,γ-Unsaturated Esters and δ-Hydroxy Esters
Kang, Suk-Ku,Kim, Sung-Gyu,Park, Dong-Chul,Lee, Jang-Sup,Yoo, Weon-Jong,Pak, Chwan Siek
, p. 9 - 10 (2007/10/02)
The acetonides, cyclic carbonates or cyclic sulfites of γ,δ-dihydroxy (E)-α,β-unsaturated esters have been found to undergo facile reductive cleavage with samarium diiodide or magnesium in methanol to provide δ-hydroxy (E)-β,γ-unsaturated esters or δ-hydr
