80698-36-8

Basic information

• Product Name: 1,12-bis(methoxycarbonyl)-4-phenyl-1,2,3,5,8,9-hexahydro-5,8-ethanonaphthalene-1,2,11,12-tetracarboxylic dianhydride
• CAS NO: 80698-36-8
• Molecular Weight: 492.439
• Mol File: 80698-36-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,12-bis(methoxycarbonyl)-4-phenyl-1,2,3,5,8,9-hexahydro-5,8-ethanonaphthalene-1,2,11,12-tetracarboxylic dianhydride(CAS DataBase Reference)
• NIST Chemistry Reference: 1,12-bis(methoxycarbonyl)-4-phenyl-1,2,3,5,8,9-hexahydro-5,8-ethanonaphthalene-1,2,11,12-tetracarboxylic dianhydride(80698-36-8)
• EPA Substance Registry System: 1,12-bis(methoxycarbonyl)-4-phenyl-1,2,3,5,8,9-hexahydro-5,8-ethanonaphthalene-1,2,11,12-tetracarboxylic dianhydride(80698-36-8)

Safety Data

• Hazardous Substances Data: 80698-36-8(Hazardous Substances Data)

Upstream product

• 530-48-3 1,1-Diphenylethylene 
• 69327-00-0 α-methoxycarbonylmaleic anhydride 

Relevant articles and documents

(Carbomethoxy)maleic Anhydride, a Highly Reactive New Dienophile and Comonomer

(Carbomethoxy)maleic anhydride (CMA), is an extremely reactive dienophile in cycloadditions with butadiene, isoprene, and chloroprene.The second-order rate constants prove it to be more reactive than tetracyanoethylene.Diels-Alder reaction with anthracene gives the normal addition product.With cyclopentadiene, the endo adduct is obtained and with furan the exo adduct.With p-metoxystyrene, anethole, and diphenylethylene, the 2:1 Wagner-Jauregg-type adducts are obtained, while with styrene both Wagner-Jauregg and Diels-Alder ene adduct are formed.Copolymers form in certain conditions.With isobutyl and phenyl vinyl ether, an inverse-lectron-demand Diels-Alder reaction with CMA yields 2-isobutoxy- or 2-phenoxy-6-methoxy-3,4-dihydro-2H-pyran-3,4-dicarboxylic anhydride.These labile dihydropyrans revert to copolymers.