80734-82-3

Basic information

• Product Name: (CO)3Fe(As(C₆H₅)3)Cl₂
• CAS NO: 80734-82-3
• Molecular Weight: 517.023
• Mol File: 80734-82-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (CO)3Fe(As(C₆H₅)3)Cl₂(CAS DataBase Reference)
• NIST Chemistry Reference: (CO)3Fe(As(C₆H₅)3)Cl₂(80734-82-3)
• EPA Substance Registry System: (CO)3Fe(As(C₆H₅)3)Cl₂(80734-82-3)

Safety Data

• Hazardous Substances Data: 80734-82-3(Hazardous Substances Data)

Upstream product

• 14375-84-9 Fe(CO)4(As(C₆H₅)3) 
• 21475-90-1 cis-[Fe(CO)4Cl₂] 
• 603-32-7 triphenyl-arsane 

Downstream Products

• 15388-81-5 (CO)3Fe(As(C₆H₅)3)I₂ 
• 603-32-7 triphenyl-arsane 

Relevant articles and documents

REACTION MECHANISM OF ALKYL HALIDES AND POLYHALIDES WITH MONO- AND DI-SUBSTITUTED DERIVATIVES OF IRON PENTACARBONYL

Mono- and di-substituted derivatives of iron pentacarbonyl react with alkyl halides and polyhalides through two parallel paths, one radical and the other molecular.Only in two cases could the two mechanisms be isolated and studied separately.The reaction between Fe(CO)3(AsPh3)2 and CCl4 to give Fe(CO)2(AsPh3)2Cl2 is radical and affected by light and duroquinone.The proposed mechanism is similar to that of the reaction between Fe(CO)3L2 and halogens.The reaction between Fe(CO)3(PMe3)2 and MeI to form Fe(CO)2PMe3)2(COMe)I is first order in both reactants, and free CO or P(Me)4I has no effect on the rate.The kinetics are interpreted in term of a concerted nucleophilic displacement involving formation of anionic intermediate.