80737-36-6

Basic information

• Product Name: Fe(C₃₂H₁₆N₈)(CO)(OP(C₆H₅)3)
• CAS NO: 80737-36-6
• Molecular Weight: 874.68
• Mol File: 80737-36-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Fe(C₃₂H₁₆N₈)(CO)(OP(C₆H₅)3)(CAS DataBase Reference)
• NIST Chemistry Reference: Fe(C₃₂H₁₆N₈)(CO)(OP(C₆H₅)3)(80737-36-6)
• EPA Substance Registry System: Fe(C₃₂H₁₆N₈)(CO)(OP(C₆H₅)3)(80737-36-6)

Safety Data

• Hazardous Substances Data: 80737-36-6(Hazardous Substances Data)

Upstream product

• 132-16-1 iron(II) phthalocyanine 
• 791-28-6 Triphenylphosphine oxide 

Relevant articles and documents

Synthesis and m?ssbauer spectroscopic studies of carbonyl derivatives of (phthalocyaninato)iron(II)

The monocarbonyl complexes of (phthalocyaninato)iron(II), FePc(CO)L, where L = N,N-diethylacetamide, pyridine, piperidine, hexamethylphosphoramide, and triphenylphosphine oxide, have been prepared and characterized, as has the dicarbonyl compound FePc(CO)2, which was isolated after exposing FePc in a hydrocarbon solvent to a high pressure of CO. The M?ssbauer spectroscopic parameters, ΔEQ and δ, both decrease upon replacement of an axial ligand of the bisadducts, FePcL2, by CO to give FePc(CO)L. These changes are consistent with a decrease in mean axial bond distances upon carbonylation and a concomitant increase in s-electron density along the z axis. The electronic basis of these structural modifications requires consideration of both cis and trans effects.