80738-00-7

Basic information

• Product Name: 7-Phenyl-4,5-dihydro-oxepin-3-one
• CAS NO: 80738-00-7
• Molecular Weight: 188.226
• Mol File: 80738-00-7.mol

Chemical Properties

• CAS DataBase Reference: 7-Phenyl-4,5-dihydro-oxepin-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 7-Phenyl-4,5-dihydro-oxepin-3-one(80738-00-7)
• EPA Substance Registry System: 7-Phenyl-4,5-dihydro-oxepin-3-one(80738-00-7)

Safety Data

• Hazardous Substances Data: 80738-00-7(Hazardous Substances Data)

Upstream product

• 80737-98-0 6-Benzoyl-dihydro-thiopyran-3-one 
• 768-03-6 Phenyl vinyl ketone 
• 156634-30-9 4-Methylene-2-phenyl-2-vinyl-[1,3]dioxolane 
• 80737-99-1 2-Methylsulfanyl-7-phenyl-4,5-dihydro-oxepin-3-one 

Relevant articles and documents

Ring expansion reaction of 2-vinyl-4-methylene-1,3-dioxolanes to 4,5-dihydro-3(2H)-oxepinones by Claisen rearrangement

2-Styryl or 2-vinyl substituted 4-methylene-1,3-dioxolanes underwent the Claisen rearrangement to obtain 4,5-dihydro-3(2H)-oxepinones in good yield. The rate of reaction followed the decreasing order: 2-phenyl-2-styryl > 2-phenyl-2-vinyl > 2 tert-butyl-2-styryl > 2-styryl.