80757-67-1Relevant academic research and scientific papers
Light-induced Reactions of Morphine Derivatives, 2. - Photoreactivity of Codeinones
Boes, Michael,Fleischhacker, Wilhelm
, p. 2002 - 2008 (2007/10/02)
The photochemical instability of the ether bridge of codeinone derivatives is due to the strain of the all-carbon ring skeleton.Irradation of the codeinones 1, 2, and 8 with light of the wavelength 254 nm causes solvolytical cleavage of the ether bridge.In contrast, derivatives with a sixmembered ring C are photostable.
