807613-09-8

Basic information

• Product Name: cis-Pt(tricyclohexylphosphine)2(H)(Si(OMe)2CH₂CH=CH₂)
• CAS NO: 807613-09-8
• Molecular Weight: 888.182
• Mol File: 807613-09-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-Pt(tricyclohexylphosphine)2(H)(Si(OMe)2CH₂CH=CH₂)(CAS DataBase Reference)
• NIST Chemistry Reference: cis-Pt(tricyclohexylphosphine)2(H)(Si(OMe)2CH₂CH=CH₂)(807613-09-8)
• EPA Substance Registry System: cis-Pt(tricyclohexylphosphine)2(H)(Si(OMe)2CH₂CH=CH₂)(807613-09-8)

Safety Data

• Hazardous Substances Data: 807613-09-8(Hazardous Substances Data)

Upstream product

• 807618-31-1 cis-Pt(tricyclohexylphosphine)2(H)(triphenylsilane(-1H)) 
• 807618-29-7 cis-Pt(tricyclohexylphosphine)2(H)(diphenylsilane(-1H)) 
• 807613-05-4 cis-Pt(tricyclohexylphosphine)2(H)(SiMe₂CH₂CH=CH₂) 
• 807613-01-0 cis-Pt(tricyclohexylphosphine)2(H)(SiMe₂Et) 
• 55664-33-0 bis(tricyclohexylphosphine)platinum⁽⁰⁾ 
• 18147-35-8 allyltrimethoxysilane 

Relevant articles and documents

Platinum bis(tricyclohexylphosphine) silyl hydride complexes

A series of platinum metal silyl hydride complexes were prepared in solution by reaction of Pt(PCy3)2 with the appropriate silane, HSiR2R′. The complex was characterized using x ray crystallography at -100°C. The platinum center was found to exhibit a distorted-square-planar geometry with angles P(1)-Pt-P(2)=113.55(3)°, P(1)-Pt-Si=146.83(3)°, and P(2)-Pt-Si=99.37(3)°. The reaction of Pt(PCy3)2 with chlorinated hydrosilanes at -78°C was also found to yield analogues complexes which isomerized to their trans isomers on warming at room temperatures.