807616-74-6Relevant academic research and scientific papers
Oxidative rearrangement of cyclic tertiary allylic alcohols with IBX in DMSO
Shibuya, Masatoshi,Ito, Shinichiro,Takahashi, Michiyasu,Iwabuchi, Yoshiharu
, p. 4303 - 4306 (2007/10/03)
(Chemical Equation Presented) A practical and environmentally friendly method for oxidative rearrangement of five- and six-membered cyclic tertiary allylic alcohols to β-disubstituted α,β-unsaturated ketones by the IBX/DMSO reagent system is described. Several conventional protecting groups (e.g., Ac, MOM, and TBDPS) are compatible under the reaction conditions prescribed.
