80764-85-8Relevant academic research and scientific papers
Biogenesis of Epidithiadioxopiperazines. Nucleophilic Additions to Benzene Oxide and sym-Oxepin Oxide
Rastetter, William H.,Chancellor, Toni,Richard, Thomas J.
, p. 1509 - 1512 (2007/10/02)
The additions of amine nucleophiles to benzene oxide (10) and to sym-oxepin oxide (14) serve as models for the biogenesis of the epidithiadioxopiperazines of the gliotoxin and aranotin family.Also reported are the additions of a thiolate and an amide anio
