80780-63-8

Basic information

• Product Name: Benzene, 1,1'-[1-propene-1,3-diylbis(thio)]bis-, (E)-
• CAS NO: 80780-63-8
• Molecular Formula: C15H14S2
• Molecular Weight: 258.408
• Mol File: 80780-63-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-[1-propene-1,3-diylbis(thio)]bis-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[1-propene-1,3-diylbis(thio)]bis-, (E)-(80780-63-8)
• EPA Substance Registry System: Benzene, 1,1'-[1-propene-1,3-diylbis(thio)]bis-, (E)-(80780-63-8)

Safety Data

• Hazardous Substances Data: 80780-63-8(Hazardous Substances Data)

Upstream product

• 5651-88-7 phenyl propargyl sulfide 
• 108-98-5 thiophenol 
• 59036-45-2 [(3-chloroprop-2-en-1-yl)sulfanyl]benzene 
• 3111-52-2 potassium thiophenolate 
• 882-33-7 diphenyldisulfane 

Downstream Products

• 102438-35-7 (E)-2-[3-(phenylthio)prop-2-en-1-yl]cyclohexanone 

Relevant articles and documents

Effect of chalcogenyl substituent on the course of allyl rearrangement at chalcogenation of 1,3-dichloropropene

Formation of 1,3-dichalcogenylpropene at the treatment of 1,3-dichloropropene with organic dichalcogenides in a redox system hydrazine hydrate–KOH is governed by the possibility of an allyl rearrangement. In the presence of bases this rearrangement proceeds via carbanion partially stabilized by the chalcogenyl substituent. The effectivity of the stabilization and consequently the probability of the rearrangement varies in the series of substituents PhS > BnS > PhSe. In the stage of the direct nucleophilic substitution of chlorine the anion PhSe?possesses the highest activity.

Nickel(II) chloride-catalyzed regioselective hydrothiolation of alkynes

Regioselective Markovnikov-type addition of PhSH to alkynes (HC≡C-R) has been performed using easily available nickel complexes. The non-catalytic side reaction leading to anti-Markovnikov products was suppressed by addition of γ-terpinene to the catalyti