808132-97-0

Upstream product

• 5813-89-8 2-thiophenylcarboxamide 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 808133-05-3 [RhCl2(η5-C5Me5)(2-(diphenylphosphino)thiophenecarboxamide)] 
• 808133-06-4 trans-[PtClMe(2-(diphenylphosphino)thiophenecarboxamide)2] 
• 808133-07-5 [PdCl(C₉H₁₂N)(2-(diphenylphosphino)thiophenecarboxamide)] 
• 808133-03-1 [PtCl₂(PPhMe₂)(2-(diphenylphosphino)thiophenecarboxamide)] 
• 808133-01-9 [PdCl(η3-C3H5)(2-(diphenylphosphino)thiophenecarboxamide)] 
• 808133-04-2 [RuCl2(η6-p-MeC6H4(i)Pr)(2-(diphenylphosphino)thiophenecarboxamide)] 

Relevant academic research and scientific papers

Spectroscopic and structural characterization of O,O′-(diphenylphosphineoxide)amidate and acetylacetonate complexes of pentacoordinate nickel(II)

Heteroleptic nickel pentacoordinate complexes with the macrocyclic ligands 2,4,4-trimethyl-1,5,9-triazacyclododec-1-ene (Me3-mcN3) or its 9-methyl derivative (Me4-mcN3), as ancillary ligands, and O,O′-(diphenylphosphineoxide)amidate ligands, [RC(O)NP(O)Ph2]? (R = C6H6 (1), C5H4N (2), C4H3S (3)), have been prepared as well as related acetylacetonate derivatives. The complexes have been studied by spectroscopic methods (IR, UV-Vis and 1H NMR). In acetone solution, the complexes exhibit isotropically shifted 1H NMR resonances. The full assignment of these resonances has been achieved using one- and two-dimensional 1H NMR techniques. The single-crystal structures of {(Me4-mcN3)Ni[OP(Ph2)NC(Tf)O]}[PF6] (9) and {(Me3-mcN3)Ni(acac)}[PF6] (10) have been established by X-ray diffraction.