808133-17-7Relevant academic research and scientific papers
Synthesis and coordination of 2-diphenylphosphinothiophenocarboxamide and bis(2,5-diphenylphosphinepicolinamide)
Milton, Heather L.,Wheatley, Matthew V.,Slawin, Alexandra M.Z.,Woollins, J. Derek
, p. 2575 - 2585 (2008/10/09)
2-Diphenylphosphinothiophenocarboxamide (dpptc) and bis(2,5- diphenylphosphinepicolinamide) (bdpppa) have been prepared and complexed with a variety of metals. Bdpptc behaves as a monodentate P donor ligand and can become bidentate by making use of the CO site. Bdpppa behaves as a P donor bridging ligand. In many cases, the X-ray structures reveal that the ligand backbone geometry is strongly influenced by intramolecular H-bonding.
