80870-09-3Relevant academic research and scientific papers
Rearrangement of 4-Oxothiochroman-1-io(bismethoxycarbonyl)methanides to Tetrahydro-1-benzothiepin-5-ones
Tamura, Yasumitsu,Takebe, Yasushi,Mukai, Chisato,Ikeda, Masazumi
, p. 2978 - 2981 (1981)
Heating thiochroman-4-ones with dimethyl diazomalonate without solvent or in refluxing toluene in the presence of copper(II) sulphate gave the corresponding bismethoxycarbonylmethanides (4) and dimethyl 5-oxo-2,3,4,5-tetrahydro-1-benzothiepin-2,2-dicarboxylates (5).Treatment of the sulphonium methanides (4) with triethylamine afforded (5).
