808765-97-1

Upstream product

• 199008-86-1 (S)-5-(tert-butyldiphenylsilyloxy)-2-methylpentanal 
• 101711-78-8 (3R)-3-propionyl-4-benzyloxazolidin-2-one 
• 124356-91-8 (4R)-3-[(2R,3S)-3-hydroxy-2-methyl-pentanoyl]-4-benzyl-oxazolidine-2-one 
• 101712-01-0 (R)-1-((R)-4-benzyl-2-oxooxazolidin-3-yl)-2-methylpentane-1,3-dione 
• 808765-96-0 (S)-4-methylhept-5-ynal 
• 80698-15-3 α-methyl-δ-valerolactone 
• 1059044-06-2 (+)-(2S)-methyl-5-tert-butoxy-pentanoic acid tert-butyl ester 
• 646994-40-3 (S)-5,6-Dibromo-1,1-dimethoxy-4-methyl-hexane 
• 808766-13-4 4-methylhept-5-yn-1-ol 
• 808766-10-1 (S)-5-(tert-Butyl-diphenyl-silanyloxy)-2-methyl-pentanoic acid ((1R,2R)-2-hydroxy-1-methyl-2-phenyl-ethyl)-methyl-amide 
• 808766-11-2 tert-butyl-(6,6-dibromo-4-methyl-hex-5-enyloxy)-diphenyl-silane 
• 808766-12-3 tert-butyl-(4-methyl-hept-5-ynyloxy)-diphenyl-silane 

Downstream Products

• 183202-73-5 (5R,6R,7S,8R,9R,12S,13E,16S,18S,19S)-6,7,8,9,10,11,12,15,16,17,18,19-dodecahydro-4,7,19-trihydroxy-2,6,8,12,14,16,18-heptamethyl-1,19:5,9-diepoxybenzo[18]annulen-3(5H)-one 
• 808766-14-5 (R)-4-benzyl-3-((2R,3S,4S,5R,8S)-3,5-dihydroxy-2,4,8-trimethylundec-9-ynoyl)oxazolidin-2-one 

Relevant academic research and scientific papers

Formal total synthesis of kendomycin by way of alkyne metathesis/gold catalysis

In an attempt to study the ability of the latest generation of alkyne metathesis catalysts to process sterically hindered substrates, two different routes to the bacterial metabolite kendomycin (1) were explored. Whereas the cyclization of the overcrowded

Total synthesis of kendomycin: A macro-C-glycosidation approach

Kendomycin, also known as (-)-TAN 2162, is a novel polyketide-derived ansamycin isolated from Streptomyces sp., which exhibits potent antagonist and agonist activities at the endothelin and calcitonin receptors, respectively. This bacterial metabolite als